Cracking breaks C-C bonds using heat and/or catalysts:
• Long alkane molecules are heated until C-C bonds break
• Random breaking produces chains of different lengths
• Some products are shorter alkanes (saturated)
• Some products are alkenes (unsaturated — contain C=C bonds)
• The process is called thermal decomposition
C₁₀H₂₂ → C₅H₁₂ + C₅H₁₀
decane → pentane + pentene
• One alkane broken into one shorter alkane + one alkene
• The alkene has a C=C double bond (unsaturated)
This deep dive covers The Chemistry of Cracking within Cracking (HT) for GCSE Chemistry. Revise Cracking (HT) in Organic Chemistry for GCSE Chemistry with 24 exam-style questions and 15 flashcards. This topic appears less often, but it can still be a useful differentiator on mixed-topic papers. It is section 2 of 14 in this topic. Use this deep dive to connect the idea to the wider topic before moving on to questions and flashcards.
Practice questions for Cracking (HT)
What is cracking in chemistry?
Describe the conditions used in thermal cracking and state the types of product formed.