Why Alkenes Are More Reactive Than Alkanes

Part of Alkenes · Section 4 of 14

How It WorksUnit: Organic ChemistryGCSE

This how it works covers Why Alkenes Are More Reactive Than Alkanes within Alkenes for GCSE Chemistry. Revise Alkenes in Organic Chemistry for GCSE Chemistry with 20 exam-style questions and 15 flashcards. This is a high-frequency topic, so it is worth revising until the explanation feels precise and repeatable. It is section 4 of 14 in this topic. Use this how it works to connect the idea to the wider topic before moving on to questions and flashcards.

⚙️ Why Alkenes Are More Reactive Than Alkanes

The C=C double bond is the source of alkene reactivity. The double bond (C=C) means two pairs of electrons are shared between the carbon atoms. One of these pairs is easier to break and provides the reaction site.

How addition reactions work:

  • A small molecule (H₂, Br₂, H₂O) approaches the C=C double bond
  • One bond of the double bond opens up
  • Each atom from the added molecule bonds to one of the two carbons
  • The result is a single bond between those carbons — a saturated product
  • This is why the reaction is called an addition reaction — atoms are added across the double bond

Why alkanes don't do this: Alkanes only have single C-C bonds, which are much stronger and require significant energy (or UV light) to break. There is no reactive double bond available. This is why alkenes are useful for making polymers — their double bonds can react — while alkanes are mainly used as fuels.

Practice questions for Alkenes

What is the general formula for alkenes?

  • A. CnH2n+2
  • B. CnH2n-2
  • C. CnH2n
  • D. CnH4
1 markfoundation

Explain what is meant by the term 'unsaturated' when applied to alkenes.

2 marksstandard

Quick recall flashcards

How are alkenes produced?
By cracking long-chain alkanes from crude oil
What are alkenes?
Unsaturated hydrocarbons containing a C=C double bond

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