Why Alkenes Are More Reactive Than Alkanes
Part of Alkenes — GCSE Chemistry
This how it works covers Why Alkenes Are More Reactive Than Alkanes within Alkenes for GCSE Chemistry. Revise Alkenes in Organic Chemistry for GCSE Chemistry with 20 exam-style questions and 15 flashcards. This is a high-frequency topic, so it is worth revising until the explanation feels precise and repeatable. It is section 4 of 14 in this topic. Use this how it works to connect the idea to the wider topic before moving on to questions and flashcards.
Topic position
Section 4 of 14
Practice
20 questions
Recall
15 flashcards
⚙️ Why Alkenes Are More Reactive Than Alkanes
The C=C double bond is the source of alkene reactivity. It consists of two bonds between the same two carbon atoms — a strong sigma bond (single bond character) and a weaker pi bond (the second bond in the double bond). The pi bond is relatively easy to break, providing the reaction site.
How addition reactions work:
- A small molecule (H₂, Br₂, H₂O) approaches the C=C double bond
- The pi bond breaks — one bond of the double bond opens up
- Each atom from the added molecule bonds to one of the two carbons
- The result is a single bond between those carbons — a saturated product
- This is why the reaction is called an addition reaction — atoms are added across the double bond
Why alkanes don't do this: Alkanes only have single C-C bonds, which are much stronger and require significant energy (or UV light) to break. There is no reactive pi bond available. This is why alkenes are useful for making polymers — their double bonds can react — while alkanes are mainly used as fuels.