ElectrolysisDiagram

Half Equations — Must Know!

Part of Electrolysis of AluminiumGCSE Chemistry

This diagram covers Half Equations — Must Know! within Electrolysis of Aluminium for GCSE Chemistry. Revise Electrolysis of Aluminium in Electrolysis for GCSE Chemistry with 20 exam-style questions and 0 flashcards. This is a high-frequency topic, so it is worth revising until the explanation feels precise and repeatable. It is section 4 of 13 in this topic. Focus on the labels, the relationships between parts, and the explanation that turns the diagram into an exam-ready answer.

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Section 4 of 13

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20 questions

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⚗️ Half Equations — Must Know!

🔵 CATHODE (−) — Reduction (Gain of electrons)

Al³⁺ + 3e⁻ → Al

Aluminium ions GAIN 3 electrons → aluminium metal atoms

Molten aluminium sinks to the bottom (it's denser than the electrolyte)

🔴 ANODE (+) — Oxidation (Loss of electrons)

2O²⁻ → O₂ + 4e⁻

Oxide ions LOSE electrons → oxygen gas molecules

Oxygen reacts with hot carbon anode: C + O₂ → CO₂

Overall equation: 2Al₂O₃ → 4Al + 3O₂

(Requires electrical energy — this is NOT a spontaneous reaction!)

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Practice Questions for Electrolysis of Aluminium

Why is aluminium extracted by electrolysis rather than by reduction with carbon?

  • A. Aluminium is less reactive than carbon
  • B. Aluminium is more reactive than carbon
  • C. Aluminium does not form ions
  • D. Carbon reacts with aluminium to form carbides
1 markfoundation

Explain why aluminium is extracted by electrolysis rather than by reduction with carbon.

2 marksstandard

Quick Recall Flashcards

Why do the carbon anodes need replacing regularly?
At 950°C, the oxygen produced at the anode reacts with the hot carbon: C + O₂ → CO₂. The carbon is gradually burned away, so the anodes must be replaced periodically.
What does OIL RIG stand for?
Oxidation Is Loss (of electrons), Reduction Is Gain (of electrons). At the Anode = Oxidation (loss). At the Cathode = Reduction (gain).

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