Bond Energies (HT)

ChemistryAQAGCSEUnit: Energy Changes
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The basics

The Currency of Chemical Reactions

📖 The Currency of Chemical Reactions

Think of bonds like bank accounts. Every bond has energy stored in it — like money saved up. To break a bond, you need to "spend" energy (it's endothermic). But when you make a new bond, you "earn" energy back (it's exothermic). Whether a reaction releases or absorbs energy overall depends on the balance sheet: did you spend more breaking old bonds, or earn more making new ones? This is the fundamental principle behind bond energy calculations — and it explains everything from why burning methane releases heat to why some reactions need continuous heating.
💰 The Bank Account Analogy

Bond energy is like a bank balance for the reaction! Breaking bonds = the reaction withdraws money (energy must be put IN). Making bonds = the reaction deposits money (energy is given OUT). If the reaction earns more than it spends — more energy released making bonds than was needed to break them — the reaction is exothermic overall. If it spends more than it earns, it is endothermic. Note: always count from the reaction's perspective. Breaking bonds costs the reaction energy (energy flows in from the surroundings); making bonds pays the reaction energy (energy flows out to the surroundings).

What is bond energy?: The energy needed to break 1 mole of a particular bond
Key terms

Chemistry glossary

What is bond energy?
The energy needed to break 1 mole of a particular bond
Spotlight
Deep Dive: Breaking and Making Bonds

Why does breaking a bond always require energy? Think about pulling a magnet off a fridge: you have to put energy in to separate them. Bonded atoms are similar — they are held together by electrical attraction between positively charged nuclei and shared electrons, and you must supply energy to pull them apart. This is

Exam tip

Earn the mark scheme marks

🧠 Memory Aids

Breaking = Bad (needs energy), Making = Magic (releases energy)

This is the most important thing to remember for bond energy questions. Break = ENDO (energy in). Make = EXO (energy out).

The formula: "IN minus OUT" = ΔH

ΔH = energy IN (breaking) − energy OUT (making)

If ΔH is negative → more OUT than IN → exothermic (more energy released than absorbed)

If ΔH is positive → more IN than OUT → endothermic (more energy absorbed than released)

Double check rule: "Negative ΔH = nice and warm (exothermic). Positive ΔH = pulls energy from surroundings (endothermic)."

Now try it yourself

Quiz · Question 1 of 25

Which statement correctly describes the energy change when chemical bonds are broken?

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