Reaction Profiles

ChemistryAQAGCSEUnit: Energy Changes
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The basics

The Energy Hill

📖 The Energy Hill

Imagine you're on a bicycle at the bottom of a hill. To get to the other side, you have to pedal hard to reach the top first — even if you're going downhill after that! Reactions work the same way. Even exothermic reactions that release energy need a "push" of energy to get started — the activation energy. It's like the energy needed to break apart the reactant molecules before new bonds can form. This is why a match won't spontaneously burst into flame even though combustion releases energy — you need to strike it first to provide that initial activation energy.
🚴 The Hill Climb Analogy

Activation energy is like cycling over a hill! Even if you're going to end up lower (exothermic), you still need to pedal up first. That initial "push" is the activation energy — it gets the reaction started — without this initial push, the molecules cannot rearrange into products. Catalysts are like tunnels through the hill — they give you an easier, lower route to the same destination!

What is activation energy?: The minimum energy particles need to react when they collide
Key terms

Chemistry glossary

What is activation energy?
The minimum energy particles need to react when they collide
Spotlight
How It Works: Reading and Drawing Reaction Profiles

A reaction profile (also called an energy level diagram) is a graph that shows how the energy of the reacting particles changes as they go from reactants to products. The y-axis shows the energy (in kJ/mol), and the x-axis shows the "progress of reaction".

Exam tip

Earn the mark scheme marks

🧠 Memory Aids

To draw the profile correctly: "Reactants UP to peak, then DOWN to products"

The curve always goes up first (activation energy required) then back down (either ending lower for exothermic or higher for endothermic).

For catalysts: "Same start, same end, lower middle"

A catalyst lowers the peak (the "middle" of the profile) but the start point (reactants) and end point (products) stay exactly the same. ΔH is unchanged.

Ea vs ΔH: "Ea is from the FLOOR, ΔH is from the START to FINISH"

Ea = from reactants level up to the peak. ΔH = from reactants level to products level. These are different measurements — do not confuse them.

Now try it yourself

Quiz · Question 1 of 28

What does activation energy represent on a reaction profile?

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