Alcohols

ChemistryAQAGCSEUnit: Organic Chemistry
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The basics

One Group That Changes Everything

🍺 One Group That Changes Everything

Take an alkane — boring, unreactive, won't dissolve in water. Now bolt on a single -OH group, and everything changes. Suddenly it dissolves in water, it reacts with sodium, it can be oxidised to a carboxylic acid. That one tiny -OH group transforms a dull hydrocarbon into something genuinely useful — a fuel (ethanol in biofuels), a solvent (methanol in industry), or the basis of alcoholic drinks. Same carbon skeleton, completely different chemistry.
🔑 The Master Key Analogy

The -OH group is like fitting a master key to a plain lock. Without it, the molecule (the lock) does nothing — inert, unreactive, chemically boring. Add the -OH group (the key) and the lock opens: the molecule can now dissolve in water, burn cleanly, and react in ways the original alkane never could. One small addition unlocks an entirely new range of chemistry.

The -OH functional group is the game-changer. This tiny addition turns unreactive alkanes into compounds that can dissolve in water, burn cleanly as fuels, and participate in countless chemical reactions.

From ancient brewery fermentation to modern industrial production, alcohols have shaped human civilisation. They're renewable fuels, essential solvents, and the starting point for making countless other chemicals.

What are alcohols?: Organic compounds containing the -OH hydroxyl functional group
Key terms

Chemistry glossary

What are alcohols?
Organic compounds containing the -OH hydroxyl functional group
Exam tip

Earn the mark scheme marks

🧠 Memory Aid: OH = Alcohol, -anol Ending

Two simple rules to remember alcohols:

  • Functional group = -OH (hydroxyl) — always at the end of the chain
  • Naming = same prefix as alkane + "-anol" ending

First four (same prefixes as alkanes):

MEPB + anol: Meth-anol, Eth-anol, Prop-anol, But-anol

For fermentation vs hydration: Fermentation = renewable, slow, low purity. Hydration = fossil fuel, fast, high purity. Think: the traditional (old) way (fermentation) is slow; the industrial (modern) way (hydration) is fast.

Now try it yourself

Quiz · Question 1 of 22

What is the functional group present in all alcohols?

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