Chemical AnalysisDiagram

Sodium Hydroxide (NaOH) Precipitate Tests

Part of Tests for IonsGCSE Chemistry

This diagram covers Sodium Hydroxide (NaOH) Precipitate Tests within Tests for Ions for GCSE Chemistry. Revise Tests for Ions in Chemical Analysis for GCSE Chemistry with 20 exam-style questions and 14 flashcards. This topic appears regularly enough that it should still be part of a steady revision cycle. It is section 3 of 14 in this topic. Focus on the labels, the relationships between parts, and the explanation that turns the diagram into an exam-ready answer.

Topic position

Section 3 of 14

Practice

20 questions

Recall

14 flashcards

Flame test colours and sodium hydroxide precipitate tests for identifying metal ions

Figure 1: Sodium hydroxide tests produce characteristic precipitate colours for different metal ions.

Sodium Hydroxide (NaOH) Precipitate Tests

Adding sodium hydroxide solution to a solution of a metal salt produces a metal hydroxide precipitate. The colour of the precipitate identifies the metal ion.

Metal IonResult with NaOHPrecipitate Formula
Al³⁺ (Aluminium)White precipitate; redissolves in excess NaOHAl(OH)₃(s)
Ca²⁺ (Calcium)White precipitate (does NOT redissolve)Ca(OH)₂(s)
Cu²⁺ (Copper)Blue precipitateCu(OH)₂(s)
Fe²⁺ (Iron II)Green precipitateFe(OH)₂(s)
Fe³⁺ (Iron III)Brown/orange precipitateFe(OH)₃(s)

Key distinguishing point: Only aluminium hydroxide Al(OH)₃ redissolves in excess NaOH, forming the soluble aluminate ion [Al(OH)₄]⁻. Calcium hydroxide does NOT redissolve — this distinguishes Al³⁺ from Ca²⁺ when both give white precipitates.

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Practice Questions for Tests for Ions

Which reagents are used to test for carbonate ions in a solution?

  • A. Add barium chloride solution, then dilute HCl
  • B. Add dilute acid, then test the gas with limewater
  • C. Add silver nitrate solution, then dilute HNO3
  • D. Add sodium hydroxide solution and warm
1 markfoundation

Describe how sodium hydroxide solution can be used to distinguish between iron(II) ions and iron(III) ions in solution, including the expected observations.

3 marksstandard

Quick Recall Flashcards

What is a precipitation reaction?
A reaction where two soluble ionic compounds react to form an insoluble precipitate. General form: A⁺(aq) + B⁻(aq) → AB(s)
How do you test for sulfate ions (SO₄²⁻)?
Add barium chloride solution + dilute HCl. White precipitate of BaSO₄ forms. Equation: Ba²⁺ + SO₄²⁻ → BaSO₄(s)

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