Chemical AnalysisTopic Summary

Topic Summary: Ion Tests

Part of Tests for IonsGCSE Chemistry

This topic summary covers Topic Summary: Ion Tests within Tests for Ions for GCSE Chemistry. Revise Tests for Ions in Chemical Analysis for GCSE Chemistry with 20 exam-style questions and 14 flashcards. This topic appears regularly enough that it should still be part of a steady revision cycle. It is section 14 of 14 in this topic. Use this topic summary to connect the idea to the wider topic before moving on to questions and flashcards.

Topic position

Section 14 of 14

Practice

20 questions

Recall

14 flashcards

Topic Summary: Ion Tests

NaOH Tests (Cations)
  • Cu²⁺ = Blue precipitate
  • Fe²⁺ = Green precipitate
  • Fe³⁺ = Brown/orange precipitate
  • Al³⁺ = White; redissolves in excess
  • Ca²⁺ = White; stays cloudy
Anion Tests
  • CO₃²⁻: add HCl → fizzing + milky limewater
  • SO₄²⁻: BaCl₂ + HCl → white precipitate BaSO₄
  • Cl⁻: AgNO₃ + HNO₃ → white AgCl
  • Br⁻: AgNO₃ + HNO₃ → cream AgBr
  • I⁻: AgNO₃ + HNO₃ → yellow AgI
Why Add Acid?
  • BaCl₂ test: HCl removes CO₃²⁻ → prevents false white ppt
  • AgNO₃ test: HNO₃ removes CO₃²⁻ → prevents false ppt
  • Always acidify BEFORE adding the test reagent
Key Ionic Equations
  • Ba²⁺ + SO₄²⁻ → BaSO₄(s)
  • Ag⁺ + Cl⁻ → AgCl(s)
  • Cu²⁺ + 2OH⁻ → Cu(OH)₂(s)
  • CO₃²⁻ + 2H⁺ → CO₂ + H₂O

Keep building this topic

Read this section alongside the surrounding pages in Tests for Ions. That gives you the full topic sequence instead of a single isolated revision point.

Practice Questions for Tests for Ions

Which reagents are used to test for carbonate ions in a solution?

  • A. Add barium chloride solution, then dilute HCl
  • B. Add dilute acid, then test the gas with limewater
  • C. Add silver nitrate solution, then dilute HNO3
  • D. Add sodium hydroxide solution and warm
1 markfoundation

Describe how sodium hydroxide solution can be used to distinguish between iron(II) ions and iron(III) ions in solution, including the expected observations.

3 marksstandard

Quick Recall Flashcards

How do you test for sulfate ions (SO₄²⁻)?
Add barium chloride solution + dilute HCl. White precipitate of BaSO₄ forms. Equation: Ba²⁺ + SO₄²⁻ → BaSO₄(s)
What is a precipitation reaction?
A reaction where two soluble ionic compounds react to form an insoluble precipitate. General form: A⁺(aq) + B⁻(aq) → AB(s)

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