Addition Polymerisation

Part of Polymers · Section 4 of 15

Deep DiveUnit: Organic ChemistryGCSE

This deep dive covers Addition Polymerisation within Polymers for GCSE Chemistry. Revise Polymers in Organic Chemistry for GCSE Chemistry with 20 exam-style questions and 14 flashcards. This topic shows up very often in GCSE exams, so students should be able to explain it clearly, not just recognise the term. It is section 4 of 15 in this topic. Use this deep dive to connect the idea to the wider topic before moving on to questions and flashcards.

➕ Addition Polymerisation

How It Works

Addition polymerisation happens when alkenes (molecules with C=C double bonds) join together. The double bond opens up, and the monomers link together to form long chains. No other products are formed — just the polymer.

General Equation:
n (C=C) → [-C-C-]ₙ
n monomers join together to make 1 polymer with n repeating units
Ethene to Poly(ethene) Example:
n H₂C=CH₂ → [-CH₂-CH₂-]ₙ
Thousands of ethene molecules join — the C=C opens, monomers link in a chain

Practice questions for Polymers

What type of monomers are needed for addition polymerisation?

  • A. Molecules with two alcohol groups
  • B. Molecules with a carbon-carbon double bond (C=C)
  • C. Molecules with a carboxyl group (-COOH) only
  • D. Molecules with an amine group (-NH₂)
1 markfoundation

Explain how addition polymerisation works. Include the role of the double bond.

3 marksstandard

Quick recall flashcards

What is a monomer?
A small molecule that can be joined together to form a polymer
What is a polymer?
A large molecule made up of many repeating units (monomers) joined together

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