Metallic Bonding, Knowledge Organiser

Knowledge Organiser: Metallic Bonding

Key Terms

  • Metallic bond: attraction between positive metal ions and delocalised electrons
  • Delocalised electrons: free electrons not fixed to any atom
  • Sea of electrons: the mobile electron cloud in a metal
  • Malleable: can be hammered into shape
  • Ductile: can be drawn into wire
  • Alloy: mixture of metals (or metal + non-metal); harder than pure metal

Must-Know Facts

  • Positive metal ions surrounded by sea of delocalised electrons
  • Conducts electricity — delocalised electrons carry charge
  • Conducts heat — electrons transfer kinetic energy
  • Malleable/ductile — layers slide, electrons maintain bond
  • High MP — strong attraction between ions and electrons
  • Conducts as a SOLID (unlike ionic compounds)
  • Alloys harder — different-sized atoms disrupt regular layers, preventing sliding
  • Steel (Fe+C), brass (Cu+Zn), bronze (Cu+Sn)

Key Equations

  • No calculation equations — descriptive topic
  • Metallic bond = electrostatic attraction between positive metal ions and delocalised electrons
  • Conductivity: delocalised electrons move freely and carry charge/energy

Common Mistakes

  • Saying metals conduct due to free ions: Metals conduct because of DELOCALISED ELECTRONS — not free ions (that is ionic compounds in solution)
  • Saying pure metals are harder than alloys: Alloys are harder — different-sized atoms disrupt the regular lattice, preventing layers from sliding
  • Forgetting metallic bonds are strong: Students often say metals have weak bonds — metallic bonds are actually strong, giving metals high melting points
  • Saying metals are brittle: Metals are malleable and ductile because layers can slide without breaking bonds (unlike ionic compounds which are brittle)

Memory Aid

  • MaDe Cm — Malleable, Ductile, Conducts (electricity and heat), high Melting point

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