Organic ChemistryTopic Summary

Knowledge Organiser: Alkanes

Part of Alkanes · GCSE GCSE Chemistry revision

This topic summary covers Knowledge Organiser: Alkanes within Alkanes for GCSE Chemistry. Topic 38: Alkanes It is section 12 of 12 in this topic. Use this topic summary to connect the idea to the wider topic before moving on to questions and flashcards.

Topic position

Section 12 of 12

Practice

20 questions

Recall

0 flashcards

Knowledge Organiser: Alkanes

Key Terms
  • Alkane — saturated hydrocarbon, CₙH₂ₙ₊₂
  • Saturated — single C-C bonds only
  • Homologous series — family with same general formula
  • General formula — CₙH₂ₙ₊₂
First Four Alkanes (MEPB)
  • Methane — CH₄ (gas)
  • Ethane — C₂H₆ (gas)
  • Propane — C₃H₈ (gas)
  • Butane — C₄H₁₀ (gas)
Properties
  • Longer chain = higher bp
  • Immiscible with water
  • Good fuels (combust in O₂)
  • Relatively unreactive
Exam Checklist
  • Saturated = single bonds, NOT "full of H"
  • Use CₙH₂ₙ₊₂ for formulas
  • Carbon always makes 4 bonds
  • Alkanes vs alkenes: sat vs unsat
Key Equations
  • General formula: CₙH₂ₙ₊₂ (n = number of carbons)
  • CH₄ + 2O₂ → CO₂ + 2H₂O (complete combustion of methane)
  • C₄H₁₀ + 6½O₂ → 4CO₂ + 5H₂O (complete combustion of butane)
Common Mistakes
  • Saying saturated means "full of hydrogen": Saturated means the molecule contains ONLY single C-C bonds — no double bonds
  • Using the wrong general formula: Alkanes = CₙH₂ₙ₊₂; alkenes = CₙH₂ₙ — confusing these loses formula marks
  • Forgetting carbon makes 4 bonds: Every carbon atom in a structural formula must have exactly 4 bonds — check this before drawing any structure
  • Saying alkanes decolourise bromine water: Alkanes do NOT decolourise bromine water — only alkenes do (they have a C=C double bond for addition reactions)

Revise this topic interactively on PrepWise — self-test mode, tap-to-reveal definitions, and Common Mistakes from examiners.

Try the interactive Knowledge Organiser — free →

Keep building this topic

Read this section alongside the surrounding pages in Alkanes. That gives you the full topic sequence instead of a single isolated revision point.

Practice Questions for Alkanes

What is the general formula for the alkane homologous series?

  • A. CₙH₂ₙ
  • B. CₙH₂ₙ₋₂
  • C. CₙHₙ
  • D. CₙH₂ₙ₊₂
1 markfoundation

Explain why the boiling point of alkanes increases as the chain length increases.

3 marksstandard

Quick Recall Flashcards

Formula for butane?
C₄H₁₀
Formula for ethane?
C₂H₆

20 questions on Alkanes — practise free

Instant marking, adaptive difficulty, and spaced repetition flashcards. Free until your GCSEs.

Try PrepWise Free