Group 7: Halogens

ChemistryAQAGCSEUnit: Atomic Structure
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The basics

The Greedy Non-Metals

📖 The Greedy Non-Metals

If alkali metals are desperate to GIVE away electrons, halogens are desperate to TAKE them. Fluorine is so aggressive it will react with almost anything — even glass! Chlorine was used as a weapon in World War I because it's so reactive and toxic. Yet these dangerous elements are essential: chlorine keeps our swimming pools clean and our drinking water safe; iodine is added to salt to prevent thyroid problems; and every time you add table salt to your food, you're eating a compound made from the explosive metal sodium and the poisonous gas chlorine. Chemistry is full of surprises!
🧲 The Magnet Analogy

Halogens are like magnets reaching for a missing piece. With 7 electrons, they're just 1 short of a full outer shell. The smaller the atom (fluorine, chlorine), the closer the outer shell is to the positive nucleus — like a stronger magnet that can pull harder. Iodine is like a weaker magnet: it's bigger, so the outer shell is further away, giving a weaker pull on that extra electron.

Will Br₂ + NaCl react?: NO — bromine is less reactive than chlorine
Key terms

Chemistry glossary

Will Br₂ + NaCl react?
NO — bromine is less reactive than chlorine
Spotlight
Why Are Halogens So Reactive? (The Opposite of Alkali Metals!)

Every halogen has 7 electrons in its outer shell — just ONE short of a full shell.

Exam tip

Earn the mark scheme marks

🧠 Memory Aids

Group 7 order: "Fluorine Chlorine Bromine Iodine Astatine" — "Fast Cars Burn In Accidents" (F, Cl, Br, I, At).

States at room temperature: "Gas Gas Liquid Solid" for F₂, Cl₂, Br₂, I₂ — the only liquid element in the group is bromine (memorise this as the exception).

Displacement rule: "More reactive = can displace less reactive" — if you can remember the order F > Cl > Br > I (decreasing reactivity), you can work out any displacement question.

Group 7 vs Group 1: "Group 1 wants to LOSE (gets easier going down), Group 7 wants to GAIN (gets harder going down)" — opposite trends for opposite processes.

Quick Check: Explain why chlorine is more reactive than iodine.

Now try it yourself

Quiz · Question 1 of 22

How many electrons do halogens have in their outer shell?

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