Gas Pressure & Temperature, Knowledge Organiser

Knowledge Organiser: Gas Pressure and Temperature

Key Terms

  • Gas pressure: force per area from particle-wall collisions
  • Absolute zero: 0 K = −273°C, minimum kinetic energy
  • Kelvin: absolute temperature scale, T(K) = T(°C) + 273

Key Facts

  • Pressure caused by particle-wall collisions
  • Higher T → faster particles → more frequent + harder collisions → higher pressure
  • As temperature rises at constant volume, pressure rises

Key Equations

  • p = F/A (Pa = N/m²)
  • T(K) = T(°C) + 273 (Edexcel: conversion only; Eduqas: also used inside gas-law calculations)
  • p₁V₁ = p₂V₂ (Boyle's law, constant temperature) — Physics only on AQA and Edexcel (14.19P); given as pV = constant on every board's equation sheet

Exam Tips

  • Particle explanation: speed + frequency + force of collisions
  • Boyle's law calculations need no Kelvin conversion on any board; only Eduqas sets pressure-law calculations, which do
  • Absolute zero: particles at minimum KE, p = 0 theoretically
  • Don't confuse pressure increase with particles getting bigger

Common Mistakes

  • Using Celsius instead of Kelvin (Eduqas only): Eduqas pressure-law calculations must use temperature in Kelvin — convert by adding 273 to the Celsius value (0°C = 273 K). Boyle's law calculations, which are the only gas calculation on AQA, Edexcel, OCR A and OCR B, need no temperature conversion at all.
  • Incomplete particle explanation for pressure increase: Must state that particles move faster, collide more frequently with the walls, AND each collision exerts a greater force — all three points are needed
  • Confusing pressure and volume changes: At constant temperature, increasing volume decreases pressure (p₁V₁ = p₂V₂); at constant volume, increasing temperature increases pressure
  • Saying absolute zero means no energy: At absolute zero (−273°C / 0 K), particles have minimum kinetic energy — they do not stop completely in the classical model
  • Forgetting units for pressure: Pressure must be in Pascals (Pa) and volume in m³ for the standard gas equations — check units carefully before substituting

Memory Aid

  • Particles move faster (higher kinetic energy)
  • More frequent collisions with walls
  • Greater force per collision → higher pressure

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